Sorry, 1860's not 1760's! 

Michael Deibert
OAS AAS LLS
Sent from my iPhone

On Feb 1, 2011, at 18:04, Marie Stewart <maric...@gmail.com> wrote:

> Hi folks.
> I must, respectfully, disagree with Ann on a point about the color Prussian
> Blue  Prussian Blue is defined as absorbing wavelengths about around 680 nm,
> causing it to appear in visible light as approximately 700 THz.  Which is a
> lovely strong blue leaning towards the violet end of the spectrum,  not to
> the green/yellow end.
> (Methods of Chemical Analysis,  1998)
> 
> I will agree with her that I misspoke when I said it was and aniline dye,
> its a cyanometalate.  I would have been more accurate to say that Prussian
> blue was one of the first chemically synthesized dyes.  Thanks for the
> redirect on that one.
> 
> (navel gazing:  We know that the dye was in the painters sphere in the early
> 1700s  (18th century), but when did it move to the dyers sphere?  Was it in
> the mid-1700s, thanks to Macquer's experiments with reduction, thereby
> giving an easily transportable salt?   Or was it used popularly, or rarely
> before that.   I'm going to go have to go research this.     Fascinating
> topic.
> 
> As a nifty side note, and a easy visual reference (although I got it from
> Wikipedia, so take it with a big grain of NaCl) the midnight blue crayon
> was once colored with and called Prussian blue.
> 
> Mari
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