Have you changed it in System>Preferences>Sound, at the bottom of the first tab?
You can change there what the multimedia keys control, so choose the frontal 
speakers or master volume.
If that doesn't work, try changing the device (just above it).

Please, let me know whether it solves your problem.

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Volume control key controls speaker & not headphones
https://bugs.launchpad.net/bugs/63544
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