Michael Konieczny:
> >> postfix/smtp[69016]: connect to ::1[::1]:10024: Operation timed out

Of course that timeout problem is outside the scope of Postfix.

> > If you don't like the ::1, specify a hostname. The logging format
> > is hostname[address]:port. If no hostname is available, it will log
> > the address instead.
> 
> OK, so log format is clarified.
> Still, it doesn't connect to ::1, but connects to 127.0.0.1.

If a connection request to ::1 fails, or results in a connection
to 127.0.0.1, then that is an issue with your IP stack, and should
be resolved in a different forum.  You're welcome to report the
resolution here, as that is relevant to Postfix.

Run the Postfix SMTP client under strace, see what syscalls it
makes, and how they fail.  http://www.postfix.org/DEBUG_README.html

        Wietse

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