Well,
You could have a look at this one, http://gtk.php.net/ Though I never had the lucury of getting anywhere with it, it has the possibility to create standalone EXE. There is (Atleast the last time i checked) still a problem with the EXE opening an extra command prompt window, which makes it look abit "unprofessional" if your thinking of applying somthing for your business customer.
That extension does not create exe files, they are normal php scripts that use gtk functions.
The "window issue" can be solved, there is some kind of wrapper available.
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