# echo | openssl s_client -connect emu.sbt.net.au:110 2>/dev/null |
openssl x509 -noout
 -enddate
unable to load certificate
139830305752976:error:0906D06C:PEM routines:PEM_read_bio:no start
line:pem_lib.c:707:Expecting: TRUSTED CERTIFICATE


Your test does not use starttls on port 110, could you retry like this?:
echo | openssl s_client -connect emu.sbt.net.au:110 -starttls pop3 2>/dev/null | openssl x509 -noout -enddate

Is the clients time / date properly configured? For me all your pop3s/imaps/smtps ports answer fine.

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