Yes, its a binary file in one of the $HOMEDIR/.gnome<something>
directories. Unless you completely understand how to edit it... it will
possibly make you unable to login. Best just use the features already
given to you to modify it.
Maybe you have permissions wrong for some files. Like, you launched
something by root, file got owner root, and now it can't be written on
logout.
try in console
chown -R user ~
where "user" is your username
Regards,
Atis
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