I use
#for satellite and smarthost-systems
.ifndef DCsmarthost
DCdefault_sh = DEBCONFsmarthostDEBCONF
DCsmarthost =
${lookup{$sender_address}lsearch{CONFDIR/smarthost_per_user}{$value}{DCdefault_sh}}
.endif
in exim4.conf.template and a smarthost_per_user file like
[EMAIL PROTECTED]: smarthost.xx.zz
[EMAIL PROTECTED]: smtp.web.de::587
see also http://www.cs.ru.nl/~tews/user-smarthost.html
Bye,
Hendrik
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