The central Bi atom is eight-coordinate in a capped distorted pentagonal
bipyramidal geometry.
The CuII ion lies on a crystallographic inversion centre and is in a
distorted octahedral environment. The central Bi atom is
eight-coordinate in a capped distorted pentagonal bipyramidal geometry.
The Cl atom and one CH group of the imidazole ring lie on twofold
rotation axes.
The CoII ion is six-coordinated by four O atoms of methanol molecules
and two water molecules in a distorted octahedral geometry.

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The bipyridine-coordinated Zn atom on the threefold axis has a
tetrahedral geometry, whereas the other Zn atom is coordinated by the O
atoms of six different dianions in an octahedral geometry. The Co atom
lies on a centre of symmetry.
The bipyridine-coordinated Zn atom on the threefold axis has a
tetrahedral geometry, whereas the other Zn atom is coordinated by the O
atoms of six different dianions in an octahedral geometry. The compound
is isostructural with an already reported Gd complex. In both molecules,
two Cu atoms are bridged by four carboxylate groups, and the fifth
coordination site of the square pyramid is occupied by the water
molecule. The axial positions are occupied by N atoms of two monodentate
dicyanamide anions. The square pyramid is completed by an aqua ligand in
the apical position.
The Cl atom and O atom of the uncoordinated water molecule both lie on
twofold rotation axes. In both molecules, two Cu atoms are bridged by
four carboxylate groups, and the fifth coordination site of the square
pyramid is occupied by the water molecule. O hydrogen bonds into a
three-dimensional network. In the crystal strucure, cations and anions
are linked into a three-dimensional network architecture by hydrogen
bonds. Each L ligand bridges five CdII atoms, generating a distinctive
three-dimensional coordination polymer. The square pyramid is completed
by an aqua ligand in the apical position. The MnII atom is coordinated
by four N atoms of two phen ligands, one Cl atom and one aqua ligand,
forming a distorted octahedral geometry.
The CuII ion lies on a crystallographic inversion centre and is in a
distorted octahedral environment.
The chains are interconnected by BDC linkers, generating a
three-dimensional framework with large voids. The CuII ion lies on a
crystallographic inversion centre and is in a distorted octahedral
environment.
The CuII ion lies on a crystallographic inversion centre and is in a
distorted octahedral environment. The two imino ligands are mutually
trans. A twofold rotation axis passes through the coordinated N atom and
the opposite C atom of the pyridyl ring of the ligand, while a threefold
rotation axis passes through the aliphatic N atom.
In the dianion, one of the sulfate groups is unidentate whereas the
other two chelate the metal atom. The CoIII centre has a distorted
octahedral geometry in both molecules. The six atoms around the metal
form a slightly distorted octahedral geometry. The MnII atom is
coordinated by four N atoms of two phen ligands, one Cl atom and one
aqua ligand, forming a distorted octahedral geometry. The Pd atoms have
approximately square planar configurations. A three-dimensional
supramolecular network is formed by intermolecular hydrogen bonds. The
Co atom lies on a centre of symmetry.
The ethyl groups of the solvent ligand are disordered in the void.
The six atoms around the metal form a slightly distorted octahedral
geometry. S interactions about an inversion center.
The chains are interconnected by BDC linkers, generating a
three-dimensional framework with large voids.
The Cl atom and one CH group of the imidazole ring lie on twofold
rotation axes. In both molecules, two Cu atoms are bridged by four
carboxylate groups, and the fifth coordination site of the square
pyramid is occupied by the water molecule. The Ni atoms both show a
square-planar coordination geometry.
A three-dimensional supramolecular network is formed by intermolecular
hydrogen bonds.



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