Am 06.04.2016 um 10:13 schrieb Stephen Kitt:
> How should I go about debugging this?

Can you attach the output of
systemctl status NetworkManager.service
systemctl --version
systemd-delta
findmnt (and contents of fstab)

I somehow guess that some directories are not accessible to NetworkManager.
Could you run systemctl edit --full NetworkManager.service.
This will create a copy in /etc/systemd/system/NetworkManager.service.
Then remove/comment out the lines

CapabilityBoundingSet=

ProtectSystem=

ProtectHome=

One-by-one. Run systemctl daemon-reload after each modification and try
to start the service.

Regards,
Michael

-- 
Why is it that all of the instruments seeking intelligent life in the
universe are pointed away from Earth?

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